23January2020

Nano-Micro Letters

Elastic Aerogels of Cellulose Nanofibers@Metal-Organic Framework for Thermal Insulation and Fire Retardancy

Shengyang Zhou1, Varvara Apostolopoulou-Kalkavoura2, Marcus Vinícius Tavares da Costa3, Lennart Bergström2, Maria Strømme1,*, Chao Xu1,*

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Nano-Micro Lett. (2020) 12: 9

First Online: 19 December 2019 (Article)

DOI:10.1007/s40820-019-0343-4

*Corresponding author. E-mail: xmaria.stromme@angstrom.uu.se (M. Strømme)chao.xu@angstrom.uu.se (C. Xu)

 

Abstract

 


Toc

Metal−organic frameworks (MOFs) with high microporosity and relatively high thermal stability are potential thermal insulation and flame retardant materials. However, the difficulties in processing and shaping MOFs have largely hampered their applications in these areas. This study outlines the fabrication of hybrid CNF@MOF aerogels by a stepwise assembly approach involving the coating and crosslinking of cellulose nanofibers (CNFs) with continuous nanolayers of MOFs. The crosslinking gives the aerogels high mechanical strength but superelasticity (80% maximum recoverable strain, high specific compression modulus of ~200 MPa cm3 g−1, and specific stress of ~100 MPa cm3 g−1). The resultant lightweight aerogels have a cellular network structure and hierarchical porosity, which render the aerogels with relatively low thermal conductivity of ~40 mW m−1 K−1. The hydrophobic, thermally stable MOF nanolayers wrapped around the CNFs result in good moisture resistance and fire retardancy. This study demonstrates that MOFs can be used as efficient thermal insulation and flame retardant materials. It presents a pathway for the design of thermally insulating, superelastic fire-retardant nanocomposites based on MOFs and nanocellulose. 


 

Keywords

Metal-organic frameworks; Nanocellulose; Superelastic aerogel, Thermal insulation; fire retardancy

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