17August2017

Nano-Micro Letters

Preparation of Sandwich-like NiCo2O4/rGO/NiO Heterostructure on Nickel Foam for High Performance Supercapacitor Electrodes

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Delong Li1,2, Youning Gong1,2, Miaosheng Wang1,3, Chunxu Pan1,2,*

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Nano-Micro Lett. (2017) 9: 16

Published Online: 28 November 2016 (Article)

DOI: 10.1007/s40820-016-0117-1

*Corresponding author. Email: cxpan@whu.edu.cn

 

Abstract

 


abstract

A kind of sandwich-like NiCo2O4/rGO/NiO heterostructure composite have been successfully anchored on nickel foam (NF) substrate via a three-step hydrothermal method with successive annealing treatment. The smart combination of NiCo2O4, reduced graphene oxide (rGO) and NiO nanostructure in the sandwich-like nano architecture shows a promising synergistic effect for supercapacitors with greatly enhanced electrochemical performance. For serving as supercapacitor electrode, the NiCo2O4/rGO/NiO heterostructure materials exhibit remarkable specific capacitance of 2644 mFcm-2 at current density of 1 mA cm-2, and excellent capacitance retentions of 97.5% after 3000 cycles. It is expected that the present heterostructure will be promising electrode materials for high performance supercapacitors.


 

Keywords

NiCo2O4; Reduced graphene oxide (rGO); NiO; Heterostructure; Supercapacitors

 

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1 Introduction

 

Supercapacitors have attracted wide attention because of their ultra-high power density, long cycling stability, fast charge/discharge rate, and bridging function for the power and energy gaps between batteries and traditional dielectric capacitors [1, 2]. Generally, the electrode materials used for supercapacitors can be divided into two categories based on the different energy storage mechanisms: electrical double layer capacitors (EDLCs) and pseudo-capacitors (PCs) [3]. In fact, PCs exhibit much larger capacitance values and energy density than EDLCs due to their fast and reversible redox reaction [4]. Therefore, considerable efforts have been focused on improving the performance of PCs. It has been recognized that the most used PCs' electrode materials, includingRuO2, NiO, Co3O4 and MnO2, possess multiple oxidation states/structures, which enable rich redox reactions on the surface of the electrodes and provide high specific capacitance. However, the poor conductivity and cycling stability of these materials restrict their applications [5-8].

More recently, mixed transition-metal oxides (MTMOs), such as single-phase ternary metal oxides with two different metal cations, typically in a spinel structure (donated as AxB3-xO4, A, B=Co, Ni, Zn, Mn, Fe, and so on), have captured much attention as promising electrode materials in electrochemical energy conversion and storage systems[9, 10].Among the MTMOs, comparing with NiO and Co3O4, the spinel nickel cobaltite (NiCo2O4) exhibits better electrical conductivity and higher electrochemical activity [9, 11]. However, the relatively weak conductivity and small specific surface area make the capacity greatly lower than the theoretical value. Therefore, numerous efforts have been made to optimize the supercapacitors performance of NiCo2O4 via various methods, including control of microstructures, crystallinity, and electrical conductivity [12-14].

Rational designed electrode materials with well-defined micro-/nanostructures are attractive methods to enhance the performance of PCs [15-18]. For example, Zhang et al. [15] reported Co3O4@NiCo2O4 nanowire arrays for PCs with an improved specific capacitance (2.04 F cm-2 at 5 m Vs-1) with respect to pure Co3O4. Liu et al. [16] synthesized a binder-free hierarchical NiCo2O4/NiO nanowire array using a facile hydrothermal method, and the composites exhibited superior pseudocapcacitive performance with high specific capacitance (2220 F g-1 at 1 A g-1). Cai et al. [17] constructed a one-dimension (1D) CNT@NiCo2O4 core-shell structural nanocable for PCs with a high capacitance of 1038 F g-1 at 0.5 A g-1.

In addition, graphene have been widely used as electrode materials due to its excellent electrical, optical, and chemical properties [19-22]. Zhang et al. [20] showed that flower-like NiCo2O4/three-dimension (3D) graphene foam exhibited a specific capacitance of 1402 F g-1 at 1 A g-1. Liu et al. [21] prepared a mesoporous NiCo2O4 nanoneedle grown on graphene networks and the composite delivered a high specific capacitance of 970 F g-1 at 20 A g-1.

In this paper, we prepared a sandwich-like NiCo2O4/rGO/NiO heterostructure composite on nickel foam via a facile hydrothermal method and subsequent annealing in the air. In the designed sandwich-like structure, the components were assembled into a uniform structure and each component could partially retain its individual traits to improve electrochemical properties. When it was used as electrode materials, it showed a much higher specific capacitance than those of materials such as NiCo2O4, NiO, and NiCo2O4/NiO. We propose that the smart combination among NiO, rGO and NiCo2O4 nanostructures may provide a synergistic effect for supercapacitors to enhance the electrochemical performance.

 

2 Experimental Section

 

2.1 Preparation NiO on NF

 

Prior to the synthesis, the nickel foam (NF) substrate was carefully cleaned with acetone, ethanol and deionized (DI) water in an ultrasound bath to remove surface impurities. In a typical procedure, the cleaned NF (approximately 1´1 cm2 for each piece) and 40 mL DI water were put into a 50 mL Teflon-lined stainless autoclave and heated at 200 °C for 24 h. The precursor products were washed with ethanol and DI water, and dried at 80 °C for 6 h. Then, the products were annealed at 350 °C for 2 h in air to obtain NiO on NF. The load mass of NiO is 0.6 mg cm-2.

 

2.2 Preparation rGO/NiO Composite on NF

 

Graphene oxide (GO) was synthesized by a modified Hummer’s method which described in detail in our previous work [22]. The rGO/NiO composites were prepared according to the following process. i) The as-synthesized GO (40 mg) was added into DI water (40 mL) and dispersed for 2h with an aid of ultra-sonication. ii) Several pieces of NiO on NF were put into the above GO dispersion, followed by soaking for 2h. iii) The mixture was then transferred into a 50 mL Teflon-lined stainless autoclave, and maintained at 200°C for 24 h. iv) As the autoclave cooled down to room temperature, the products were washed for several times with DI water and ethanol, and dried at 60 °C for 4 h in vacuum to obtain the rGO/NiO composites on NF. The load mass of rGO/NiO was 0.6 mgcm-2(the mass of rGO was too small to be weighed out).

 

2.3 Preparation Sandwich-like NiCo2O4/rGO/NiO Heterostructure Composites on NF

 

The typical synthesis process of sandwich-like NiCo2O4/rGO/NiO heterostructure composites on NF are as follows. Firstly, 0.5 g urea, 1 mmol Co(NO3)2·6H2O and 0.5 mmol Ni(NO3)2·6H2O were dissolved into 40 mL DI water, and stirred for 30 min to form a uniform solution. Then, a piece of rGO/NiO on NF was put into the above solution and soaked for 2h. The mixture was transferred into a 50 mL Teflon-lined stainless autoclave, and maintained at 120 °C for 6 h. As the autoclave cooled down to room temperature, the precursor products were washed for several times with DI water and ethanol, and dried at 60°C for 4 h under vacuum. Finally, the precursor were annealed at 350°C for 2 h to obtain sandwich-like NiCo2O4/rGO/NiO heterostructure on NF. The NiCo2O4 or the NiCo2O4/NiO composite on NF were fabricated under identical conditions, in which the substrate was changed into NF or NiO on NF. The load mass of the NiCo2O4/rGO/NiO, NiCo2O4/NiO, and NiCo2O4 are 1.6, 1.4, and 0.9 mg cm-2, respectively.

 

2.4 Materials Characterizations

 

The phase structures of the samples were characterized by using an X-ray diffraction spectrometer (XRD, D8 Advanced XRD; Bruker AXS, Karlsruhe, Germany) with Cu Kα radiation. The morphologies of the samples were observed by using a scanning electron microscope (SEM, S-4800, Hitachi High-Technologies Corporation, Japan). Raman spectra were measured in a laser scanning confocal micro-Raman spectrometer (LabRAM HR, HORIBA, France).

 

2.5 Electrochemical Measurement

 

The electrochemical tests were performed in a 6 M KOH aqueous electrolyte solution at room temperature. The electrochemical properties of the samples were evaluated using a CHI660D Electrochemical Working Station in a three-electrode system, wherein the samples on nickel foam as the working electrode (WE), platinum as the counter electrode, and saturated calomel electrode (SCE) electrode as the reference electrode.

The specific capacitance (C) was calculated from the slope of each discharge curve, according to the equation C = (I´Δt)/(ΔV´S), where I is the constant discharge current, Δt is the discharge time, ΔV is the voltage difference in discharge (exclude IR drop), and S is the area of each active materials [19, 23]. Electrochemical impedance spectroscopy (EIS) measurements were made in the frequency range of 0.1-100,000 Hz by applying an AC voltage with 5 mV perturbation.

 

3 Results and Discussion

 

The general preparation process and the resulting novel supercapacitors electrode heterostructure materials are schematically illustrated in Fig. 1. A multi-step hydrothermal method followed by a calcination process was employed to prepare the sandwich-like NiCo2O4/rGO/NiO heterostructure composite.

Figure 1 Schematic illustration of the preparation process of the sandwich-like NiCo2O4/rGO/NiO heterostructure.

Figure 1 Schematic illustration of the preparation process of the sandwich-like NiCo2O4/rGO/NiO heterostructure.

The XRD patterns of as-prepared samples are shown in Fig. 2a, in which the samples are NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO, respectively. As the active materials directly grew on the surface of NF, the strong typical peaks were ascribed to NF substrate. The diffraction peaks of NiCo2O4 and NiO were also observed clearly. However, the diffraction peak of rGO was not identified due to the low mass content of rGO. In the Raman spectra of the samples as shown in Fig. 2b, the peaks of rGO were clearly observed at 1349.8 and 1590.2 cm-1, which are corresponding to the D and G band of rGO. The peaks located at 151.6, 457.6, 455.2, 505.7, 656.6, and 1096.4 cm-1are respectively correspond to the F2g, Eg, LO, A1g, and 2LO modes of NiCo2O4, while the peak located at 501.3 cm-1 belongs to NiO. These results are well consistent with the previously reported literatures [18, 21, 24].

Figure 2 XRD patterns, and b Raman spectra of the NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO.

Figure 2 XRD patterns, and b Raman spectra of the NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO.

Figure 3 shows the top view SEM images of the samples of NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO. Comparing with original NF, the NF surface is covered with the NiO nanoplates after the first hydrothermal treatment (see Fig. 3b). And then an rGO layer was observed on the surface of the NiO nanoplates after the second hydrothermal treatment, as shown in Fig. 3c. Figure 3d-f indicates that NiCo2O4 nanoneedles are directly grown on the surfaces of the NF, NiO, and rGO/NiO, respectively. Obviously, the morphology of NiCo2O4 is not affected by the substrates. The cross-section SEM image of the sandwich-like NiCo2O4/rGO/NiO heterostructure composite is shown in Fig. 4, in which the NiCo2O4 nanoneedle, NiO nanoplate and NF substrate appear obviously. The rGO thin film was too thin to be observed here.

Figure 3 SEM morphology of the samples: a NF, bNiO, c G/NiO, d NiCo2O4, eNiCo2O4/NiO, and fNiCo2O4/rGO/NiO.

Figure 3 SEM morphology of the samples: a NF, bNiO, c G/NiO, d NiCo2O4, eNiCo2O4/NiO, and fNiCo2O4/rGO/NiO.

Figure 4 SEM Cross section view of NiCo2O4/rGO/NiO.

Figure 4 SEM Cross section view of NiCo2O4/rGO/NiO.

The electrochemical properties of the samples were measured by various techniques involving cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and EIS in a three electrode system. Figure 5a illustrates the CV curves of the sandwich-like NiCo2O4/rGO/NiO heterostructure electrode at various scan rates of 1-10 mVs-1 in the potential range of 0-0.6 V vs. SCE. A couple pair of redox peaks was observed in the CV curves, indicating that the measured capacitance was mainly based on the redox mechanism [25].

Figure 5 Electrochemical properties of the sandwich-like NiCo2O4/rGO/NiO heterostructure: a CV curves with scan rate change, and b GCD curves with current density change.

Figure 5 Electrochemical properties of the sandwich-like NiCo2O4/rGO/NiO heterostructure: a CV curves with scan rate change, and b GCD curves with current density change.

In fact, during the charging-discharging process, there exists valence state changes of Co3+/Co4+, as well as M2+/M3+ (M = Co or Ni) on the surface of the electrode materials, where fast and reversible Faradaic reactions occur. The Faradaic reactions of NiCo2O4 in the alkaline electrolyte would proceed according to the following reaction equations [25, 26],

NiCo2O4 + OH- ↔ NiOOH + 2CoOOH +2e-          (1)

CoOOH + OH- ↔ CoO2 + H2O + e-            (2)

For NiO, the surface Faradaic reactions in the alkaline electrolyte will proceed according to the following equations [27, 28],

NiO + OH- ↔ NiOOH + e-            (3)

However, the electrochemical redox potentials of the M2+/M3+ and Co3+/Co4+ transitions are so close that the observed redox peaks are overlapped [26, 27].

With increasing the scan rate, the redox peaks maintain stable, indicating excellent kinetic reversibility at a large scan rate. To further calculate the specific capacitance and understand the rate capability of the NiCo2O4/rGO/NiO composite electrode, the charge/discharge measurements were performed. Figure 5b gives the discharge curves of the NiCo2O4/rGO/NiO electrode at various current density. The corresponding specific capacitance was calculated to be 2644 mF cm-2 at a low current density (1 mAcm-2), and 1821.6 mF cm-2 at a high current density (100 mA cm-2).

In order to confirm the outstanding electrochemical performance of the sandwich-like NiCo2O4/rGO/NiO heterostructure composite, the electrochemical properties of the NiO, rGO/NiO, NiCo2O4, and NiO/NiCo2O4 were also tested. For comparison, CV curves of the NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO at a scan rate of 5 mV s-1are illustrated in Fig. 6a.Clearly, the enclosed area of the sandwich-like NiCo2O4/rGO/NiO heterostructure material is much larger than those of other samples, indicating that the NiCo2O4/rGO/NiO has a lager areal capacitance. Figure 6b shows the discharge capacitance of the NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO at a current density of 1 A cm-2. Similarly, the sandwich-like NiCo2O4/rGO/NiO heterostructure material delivers a higher specific capacitance than others.

Figure 6 Electrochemical properties of the samples: a CV curves at 5 mVs-1, b GCD curves at 1 mAcm-2, c the corresponding specific capacitance, and d EIS plots of the samples (inset is the enlarged plot of the high-frequency regions).

Figure 6 Electrochemical properties of the samples: a CV curves at 5 mVs-1, b GCD curves at 1 mAcm-2, c the corresponding specific capacitance, and d EIS plots of the samples (inset is the enlarged plot of the high-frequency regions).

Figure 6c illustrates specific capacitance as a function of current density of the NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO. Within the current density range of 1-100 mA cm-2, the area specific capacitance of the samples has the order of NiOrGO/NiONiCo2ONiCo24/NiONiCo2O4/rO/NiO. Since the area specific capacitance of NiO and rGO/NiO are too small at a high current density of 100 mA cm-2, the data is not presented in Fig. 6c. The area specific capacitances of the NiO, rGO/NiO, NiCo2O4, iCo2O4/NiO, and NiCo2O4/rGO/NiO were 374, 516.8, 975.5, 2092, and 2644 mF cm-2 at a low current density (1 mA cm-2), respectively.

In general, EIS is usually used to investigate the performance of electrochemical capacitors, such as internal resistance and capacity, etc. [18, 19]. The EIS data were commonly analyzed by using Nyquist plots, in which the frequency response of the electrode/electrolyte system and the plots of the imaginary component (Z″) of the impedance against the real component (Z′) are presented [29]. As shown in Fig. 6d, the EIS curves exhibit similar forms with unconspicuous semicircle in the high frequency region and an almost straight sloping line in the low frequency region. The unconspicuous semicircle region indicates low faradaic resistance of the materials and good electrical conductivity between the samples and nickel foam [30, 31].

Cycling stability is another critical factor in evaluating the electrochemical properties of supercapacitors. The cycling stability of the sandwich-likeNiCo2O4/rGO/NiO heterostructure was evaluated by the repeated GCD measurement at current density of 30 mA cm-2, as shown in Fig. 7. Obviously, the specific capacitance of the NiCo2O4/rGO/NiO composite slightly decreases to 97.5 % for the first cycle after 3000 time’s tests, demonstrating the excellent cycling stability.

Figure 7 Cycle performance of the NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO at current density of 30 mA cm-2.

Figure 7 Cycle performance of the NF, NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO at current density of 30 mA cm-2.

The morphology of the sandwich-like NiCo2O4/rGO/NiO heterostructure after cycling test was further investigated (see Fig. 8).Obviously, the morphology and structure of the NiCo2O4/rGO/NiO are well-preserved even after 3000 time’s cycling. As shown in Fig. 8b, the NiCo2O4 nanoneedles could be seen obviously even after 3000 time’s charge-discharge test. However, compared with the initial morphology (shown in Fig. 8a), some tips of the NiCo2O4 nanoneedles are broken during the charge-discharge process. This maybe reduce the specific capacitance.

Figure 8 SEM images of the NiCo2O4/rGO/NiO heterostructures: a before, and b after cycle test.

Figure 8 SEM images of the NiCo2O4/rGO/NiO heterostructures: a before, and b after cycle test.

All above results confirm that the sandwich-like NiCo2O4/rGO/NiO heterostructure can improve the electrochemical performance for supercapacitor application. The possible mechanism may be ascribed to as follows: i) NiCo2O4 is a kind of p-type semiconductor materials. If it is coupled with other semiconductors, it will introduce impurity band effect which can greatly enhance the electrical conductivity as electrode materials [32-34]. The unique structure characteristics of the NiCo2O4/rGO/NiO composite present a promising candidate for high performance supercapacitors electrode materials. ii) The 2D NiO nanoplates, 1D NiCo2O4 nanoneedles, and 2D rGO film constructed to 3D porous structure on NF, allow completely exposing to the electrolyte, and thus optimize the electrochemical accessibility [26, 27]. iii) The hierarchical architecture directly grew from the current collector avoids the use of binders and substantially reduces the dead volume in the electrode, and therefore would be favorable for the migration of hydrated ions in the electrolyte to the surface of the electrode [15, 35]. iv) The existence of graphene enhances the conductivity, and therefore enhances the specific capacitance. Also the flexible graphene between NiO and NiCo2O4 could buffer against the local volume change during the charge-discharge process, as well as alleviate the pulverization and aggregation of the electrode material [36-38]. v) Moreover, the synergistic effect of each component would lead to fast ion/electron transfer and enhance flexibility, which finally results in the improvement of electrochemical performance.

 

4 Conclusions

 

The sandwich-like NiCo2O4/rGO/NiO heterostructure composites with high electrochemical performance were synthesized on nickel foam directly via a three-step hydrothermal strategy. The as-fabricated heterostructure composites exhibit excellent electrochemical performance including high specific capacitance, good electrochemical stability and excellent rate capability. Its remarkable enhanced electrochemical performance is attributed to the unique hierarchical sandwich-like structure and the synergistic effects among NiCo2O4, rGO, and NiO. The results suggest that the sandwich-like NiCo2O4/rGO/NiO heterostructure composites will be promising electrode materials for high performance sustainable energy storage devices.

 

Acknowledgements

 

This work was supported by the Special Fund for the Development of Strategic Emerging Industries of Shenzhen City of China (no.JCYJ20140419141154246), the National Nature Science Foundation of China (no. 11174227), and Chinese Universities Scientific Fund.

 

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Citation Information

Delong Li, Youning Gong, Miaosheng Wang, Chunxu Pan, Preparation of Sandwich-like NiCo2O4/rGO/NiO Heterostructure on Nickel Foam for High Performance Supercapacitor Electrodes. Nano-Micro Lett. (2017) 9: 16. http://dx.doi.org/10.1007/s40820-016-0117-1

History

Received: 1 September 2016 / Accepted: 24 October 2016


Additional Info

  • Type of Publishing: JOUR - Journal
  • Title:

    Preparation of Sandwich-like NiCo2O4/rGO/NiO Heterostructure on Nickel Foam for High Performance Supercapacitor Electrodes

  • Author: Delong Li, Youning Gong, Miaosheng Wang, Chunxu Pan
  • Year: 2017
  • Volume: 9
  • Issue: 2
  • Journal Name: Nano-Micro Letters
  • Publisher: OPEN ACCESS HOUSE SCIENCE & TECHNOLOGY
  • ISSN: 2150-5551
  • URL: http://dx.doi.org/ 10.1007/s40820-016-0117-1
  • Abstract:

    A kind of sandwich-like NiCo2O4/rGO/NiO heterostructure composite have been successfully anchored on nickel foam (NF) substrate via a three-step hydrothermal method with successive annealing treatment. The smart combination of NiCo2O4, reduced graphene oxide (rGO) and NiO nanostructure in the sandwich-like nano architecture shows a promising synergistic effect for supercapacitors with greatly enhanced electrochemical performance. For serving as supercapacitor electrode, the NiCo2O4/rGO/NiO heterostructure materials exhibit remarkable specific capacitance of 2644 mFcm-2 at current density of 1 mA cm-2, and excellent capacitance retentions of 97.5% after 3000 cycles. It is expected that the present heterostructure will be promising electrode materials for high performance supercapacitors.

  • DOI: 10.1007/s40820-016-0117-1